краткость - сестра таланта :)
pw groupmod "имя_группы" -m "кого_к_ней_добавить"
А якщо Вам щось ще потрібно від цієї команди, ливіться man:
PW(8) FreeBSD System Manager's Manual PW(8)
NAME
pw — create, remove, modify & display system users and groups
SYNOPSIS
pw [-V etcdir] useradd [name|uid] [-C config] [-q] [-n name] [-u uid]
[-c comment] [-d dir] [-e date] [-p date] [-g group] [-G grouplist]
[-m] [-M mode] [-k dir] [-w method] [-s shell] [-o] [-L class]
[-h fd | -H fd] [-N] [-P] [-Y]
pw [-V etcdir] useradd [name|uid] -D [-C config] [-q] [-b dir] [-e days]
[-p days] [-g group] [-G grouplist] [-k dir] [-M mode] [-u min,max]
[-i min,max] [-w method] [-s shell] [-y path]
pw [-V etcdir] userdel [name|uid] [-n name] [-u uid] [-r] [-Y]
pw [-V etcdir] usermod [name|uid] [-C config] [-q] [-n name] [-u uid]
[-c comment] [-d dir] [-e date] [-p date] [-g group] [-G grouplist]
[-l name] [-m] [-M mode] [-k dir] [-w method] [-s shell] [-L class]
[-h fd | -H fd] [-N] [-P] [-Y]
pw [-V etcdir] usershow [name|uid] [-n name] [-u uid] [-F] [-P] [-7] [-a]
pw [-V etcdir] usernext [-C config] [-q]
pw [-V etcdir] groupadd [group|gid] [-C config] [-q] [-n group] [-g gid]
[-M members] [-o] [-h fd | -H fd] [-N] [-P] [-Y]
pw [-V etcdir] groupdel [group|gid] [-n name] [-g gid] [-Y]
pw [-V etcdir] groupmod [group|gid] [-C config] [-q] [-n name] [-g gid]
[-l name] [-M members] [-m newmembers] [-d oldmembers] [-h fd | -H fd]
[-N] [-P] [-Y]
pw [-V etcdir] groupshow [group|gid] [-n name] [-g gid] [-F] [-P] [-a]
pw [-V etcdir] groupnext [-C config] [-q]
pw [-V etcdir] lock [name|uid] [-C config] [-q]
pw [-V etcdir] unlock [name|uid] [-C config] [-q]
DESCRIPTION
The pw utility is a command-line based editor for the system user and
group files, allowing the superuser an easy to use and standardized way
of adding, modifying and removing users and groups. Note that pw only
operates on the local user and group files. NIS users and groups must be
maintained on the NIS server. The pw utility handles updating the
passwd, master.passwd, group and the secure and insecure password data‐
base files, and must be run as root.
The first one or two keywords provided to pw on the command line provide
the context for the remainder of the arguments. The keywords user and
group may be combined with add, del, mod, show, or next in any order.
(For example, showuser, usershow, show user, and user show all mean the
same thing.) This flexibility is useful for interactive scripts calling
pw for user and group database manipulation. Following these keywords,
you may optionally specify the user or group name or numeric id as an
alternative to using the -n name, -u uid, -g gid options.
...
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